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Korean J. Met. Mater.
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Korean Journal of Metals and Materials
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Enhanced Thermoelectric Transport Properties in Cu-added Bi
2
Se
3
Polycrystalline Alloys
Hyungyu Cho, TaeWan Kim, Seung Min Kang, Sanghyun Park, Sang-il Kim
Korean J. Met. Mater.
2023;61(6):431-436. Published online 2023 May 18
DOI:
https://doi.org/10.3365/KJMM.2023.61.6.431
Abstract
The addition of Cu to layered Bi
2
Te
3
-based thermoelectric alloys has been studied as an effective way to enhance thermoelectric transport properties. In this study, the influence of adding Cu to Bi
2
Se
3
alloys, which have the same rhombohedral crystal structure as Bi
2
Te
3
, was investigated by synthesizing a series of Cu
x
Bi
2
Se
3
(
x
.....
More
Improved Thermoelectric Performance of Cu
3
Sb
1−x−y
Sn
x
In
y
Se
4
Permingeatites Double-Doped with Sn and In
Ho-Jeong Kim, Il-Ho Kim
Korean J. Met. Mater.
2023;61(6):422-430. Published online 2023 May 18
DOI:
https://doi.org/10.3365/KJMM.2023.61.6.422
Abstract
Cu–Sb–Se ternary chalcogenide compounds composed of earth-abundant low-toxicity elements are attracting attention as economical and ecofriendly semiconductors. Among them, permingeatite (Cu
3
SbSe
4
) is a potential thermoelectric material with high Seebeck coefficient and low lattice thermal conductivity. However, it is necessary to improve its thermoelectric properties through doping, as it has low.....
More
Gadolinium-Doped CeO
2
Gas Sensor for H
2
S Sensing
Changhyun Jin, Sangwoo Kim, Dong Eung Kim, Ali Mirzaei, Jong Wook Roh, Sun-Woo Choi, Myung Sik Choi
Korean J. Met. Mater.
2023;61(6):414-421. Published online 2023 May 18
DOI:
https://doi.org/10.3365/KJMM.2023.61.6.414
Abstract
Dihydrogen sulfide (H
2
S) gas has a flammable nature and is one of the most toxic and dangerous gases. Even small concentrations can be fatal to humans. Herein, we investigated the H
2
S gas-sensing features of commercial pristine cerium oxide (CeO
2
) and gadolinium (Gd)-doped CeO
2
(GDC) nanoparticles. First, the sensing materials.....
More
Bytizite Cu
3
SbSe
3
: Solid-State Synthesis and Thermoelectric Performance
Go-Eun Lee, Il-Ho Kim
Korean J. Met. Mater.
2023;61(5):363-370. Published online 2023 Apr 20
DOI:
https://doi.org/10.3365/KJMM.2023.61.5.363
Abstract
Bytizite (Cu
3
SbSe
3
) has attracted interest as a promising thermoelectric material because of its ultralow thermal conductivity; however, there are few experimental studies. This study investigated the optimal processing conditions for the synthesis of Cu
3
SbSe
3
using mechanical alloying (MA) and hot pressing (HP). The MA powder exhibited an orthorhombic Cu
3
SbSe
3
.....
More
Effects of Sn and In Double-Doping on the Thermoelectric Performance of Cu
3
Sb
1-x-y
Sn
x
In
y
S
4
Famatinites
Sang Yun, Il-Ho Kim
Korean J. Met. Mater.
2023;61(5):355-362. Published online 2023 Apr 20
DOI:
https://doi.org/10.3365/KJMM.2023.61.5.355
Abstract
Famatinite (Cu
3
SbS
4
) is a promising p-type thermoelectric material because of its low lattice thermal conductivity and high Seebeck coefficient. In this study, famatinite powders, double-doped with Sn (a B
IV
group element) and In (a B
III
group element) to give Cu
3
Sb
1-x-y
Sn
x
In
y
S
4
(0.02 ≤ x ≤ 0.12 and 0.06 ≤.....
More
Effect of added TiO
2
on the mechanical properties of sintered Al
2
O
3
insulator
Ri Joo Kim, Han Gyeol Jeong, Ye Ji Son, So Yeon Si, Sung-Soo Ryu, Sang Ki Ko, Hyun Seon Hong
Korean J. Met. Mater.
2023;61(5):330-337. Published online 2023 Apr 20
DOI:
https://doi.org/10.3365/KJMM.2023.61.5.330
Abstract
The effect of TiO
2
additive concentration and sintering temperatures on the densification of alumina (Al
2
O
3
) ceramics were investigated. Densified alumina specimens were prepared by uniaxial pressing at a pressure of 60 MPa followed by isothermal heating at either 1400, 1500, or 1600 o C for 2 h. The relative.....
More
Phase, Crystal Structure, and Thermoelectric Performance of Cubic Skinnerite Cu
3
Sb
1-y
Fe
y
S
3
Synthesized by Mechanical Alloying
Sang Jun Park, Il-Ho Kim
Korean J. Met. Mater.
2023;61(4):277-283. Published online 2023 Mar 22
DOI:
https://doi.org/10.3365/KJMM.2023.61.4.277
Abstract
Skinnerite (Cu
3
SbS
3
) has recently attracted attention as a promising thermoelectric material because of its low thermal conductivity. In this study, we performed the solid-state synthesis of Fe-doped skinnerite Cu
3
Sb
1-y
Fe
y
S
3
(y = 0.02−0.06) using mechanical alloying and hot pressing, and examined the samples’ thermoelectric properties relative to Fe doping content. All.....
More
Solid-State Synthesis and Thermoelectric Performance of Cu
3
Sb
1−y
B
III
y
Se
4
(B
III
= Al, In) Permingeatites
Ho-Jeong Kim, Il-Ho Kim
Korean J. Met. Mater.
2023;61(4):269-276. Published online 2023 Mar 22
DOI:
https://doi.org/10.3365/KJMM.2023.61.4.269
Abstract
Permingeatite (Cu
3
SbSe
4
) is a promising thermoelectric material with narrow bandgap energy and large carrier effective mass. However, doping is required to improve its electrical conductivity and thermoelectric properties. In this study, Cu
3
Sb
1−y
(Al/In)
y
Se
4
doped with B
III
-group elements (Al or In) at the Sb sites was synthesized using mechanical alloying followed by.....
More
Electrical, Thermal, and Thermoelectric Transport Properties of Co-Doped
n
-type Cu
0.008
Bi
2
Te
2.6
Se
0.4
Polycrystalline Alloys
Okmin Park, TaeWan Kim, Minsu Heo, Sang Jeong Park, Se Woong Lee, Hyun Kyu Cho, Sang-il Kim
Korean J. Met. Mater.
2023;61(3):206-212. Published online 2023 Feb 24
DOI:
https://doi.org/10.3365/KJMM.2023.61.3.206
Abstract
Bi
2
Te
3
-based alloys have been extensively studied as thermoelectric materials near room temperature. In this study, the electrical, thermal, and thermoelectric transport properties of a series of Co-doped
n
-type Cu
0.008
Bi
2
Te
2.6
Se
0.4
polycrystalline alloys (Cu
0.008
Bi
2−x
Co
x
Te
2.6
Se
0.4
,
x
= 0, 0.03, 0.06, 0.09 and 0.12) are investigated. The electrical conductivity of the Cu
0.008
Bi
1.97
Co
0.03
Te
2.6
Se
0.4
(
x
=.....
More
Interfacial Layer Effect on the Adhesion of the Ultra-Hard Thick TAC Film Deposition
Sang-Won Lim, Jeung-Soo Huh
Korean J. Met. Mater.
2023;61(3):157-169. Published online 2023 Feb 24
DOI:
https://doi.org/10.3365/KJMM.2023.61.3.157
Abstract
Carbon-based thin film tool coatings, such as diamond-like carbon (DLC), have excellent lowfriction and anti-sticking properties. These thin films are widely used for the cutting and machining of increasingly widely-used lightweight non-metallic and non-ferrous metal materials, as a part of countermeasures against global warming. However, non-metallic and non-ferrous metal materials.....
More
Thermal and Mechanical Properties of Cu-Graphite Composites with Spatial Anisotropy
Geon Hong Ryu, Changil Son, Jeffrey C. Suhling, Jiseok Lee, Sangha Park, Myunghwan Byun
Korean J. Met. Mater.
2023;61(2):120-125. Published online 2023 Jan 27
DOI:
https://doi.org/10.3365/KJMM.2023.61.2.120
Abstract
In the present study, we analyzed the thermal and mechanical properties of Cu-graphite composites (CGCs) with spatially anisotropic graphite layers. These composites were fabricated using a combination of electroless plating and spark plasma sintering (SPS) processes. Thermal conductivities and thermal expansion coefficients of the composites were measured using differential thermal.....
More
Bandgap Reduction and Enhanced Photoelectrochemical Water Electrolysis of Sulfur-doped CuBi
2
O
4
Photocathode
Eunhwa Kim, Sanghan Lee, Sangwoo Ryu
Korean J. Met. Mater.
2023;61(2):115-119. Published online 2023 Jan 27
DOI:
https://doi.org/10.3365/KJMM.2023.61.2.115
Abstract
As interest in hydrogen energy grows, eco-friendly methods of producing hydrogen are being explored. CuBi
2
O
4
is one of the p-type semiconductor cathode materials that can be used for photoelectrochemical hydrogen production via environment-friendly water electrolysis. CuBi
2
O
4
has a bandgap of 1.5 – 1.8 eV which allows it to photogenerate electrons.....
More
Fabrication of Self-Healable, Robust, and Superhydrophobic Nanocomposite Films
Siwoo Park, Young-Geun Ha
Korean J. Met. Mater.
2023;61(1):54-59. Published online 2022 Dec 28
DOI:
https://doi.org/10.3365/KJMM.2023.61.1.54
Abstract
Despite the recent advances in nature-inspired superhydrophobic surfaces with multifunctional properties such as self-healing, self-cleaning, antibacterial material, anti-biofouling, and oil-water separation in various industrial applications, there have been very few reports of robust superhydrophobic surfaces fabricated via a low-cost method. Herein, we report a rationally designed, self-healable, robust, and superhydrophobic.....
More
Enhanced Thermoelectric Performance of Sn-Doped Permingeatites Cu
3
Sb
1-y
Sn
y
Se
4
Ji-Hee Pi, Go-Eun Lee, Il-Ho Kim
Korean J. Met. Mater.
2023;61(1):46-53. Published online 2022 Dec 28
DOI:
https://doi.org/10.3365/KJMM.2023.61.1.46
Abstract
In this study, Cu
3
Sb
1-y
Sn
y
Se
4
(0 ≤ y ≤ 0.08) permingeatites were synthesized via mechanical alloying followed by hot pressing. The phase transformation, microstructure, charge transport parameters of the permingeatites, and their thermoelectric properties were analyzed. The permingeatites were present in a single phase with a tetragonal structure, and secondary phases.....
More
Transition to n-type Thermoelectric Conduction in Ni-doped FeSe
2
Alloys
Young Bin An, Sang Jeong Park, Okmin Park, Sang-il Kim
Korean J. Met. Mater.
2022;60(12):926-932. Published online 2022 Nov 25
DOI:
https://doi.org/10.3365/KJMM.2022.60.12.926
Abstract
We investigated the effect of Ni doping on the electrical, thermal, and thermoelectric transport properties of FeSe
2
polycrystalline alloys. FeSe
2
alloys exhibit both n-type and p-type conduction at different temperatures and thus their practicality as a thermoelectric material is somewhat limited. In this study, Fe
1-x
Ni
x
Se
2
polycrystalline samples with
x
=.....
More
Cited By 1
Electrical, Thermal, and Thermoelectric Transport Properties of Se-doped Polycrystalline Re
2
Te
5
Se Woong Lee, Okmin Park, Hyun-Sik Kim, Won-Seon Seo, Sang-il Kim
Korean J. Met. Mater.
2022;60(12):919-925. Published online 2022 Nov 25
DOI:
https://doi.org/10.3365/KJMM.2022.60.12.919
Abstract
Re
2
Te
5
is considered a potential thermoelectric material because of its intrinsically low thermal conductivity, due to its complex crystal structure. Herein, a series of Se-doped Re
2
Te
5
(Re
2
Te
5-x
Se
x
,
x
= 0, 0.2, 1, and 2) samples were synthesized, and their electrical and thermal transport properties were investigated. Pure orthorhombic Re
2
Te
5
phases.....
More
Cited By 2
Thermoelectric Properties of Cu-added Polycrystalline Bi
2
O
2
Se Oxyselenide
Si-young Bae, Se Woong Lee, Hyun-Sik Kim, Okmin Park, Hyunjin Park, Won-Seon Seo, Sang-il Kim
Korean J. Met. Mater.
2022;60(12):912-918. Published online 2022 Nov 25
DOI:
https://doi.org/10.3365/KJMM.2022.60.12.912
Abstract
Bi
2
O
2
Se oxyselenide has been actively studied as a potential
n
-type thermoelectric material because of its intrinsically low thermal conductivity and high Seebeck coefficient (S). However, Bi
2
O
2
Se has very low electrical conductivity (σ), resulting in relatively poor thermoelectric performance. Herein, we investigate the effect of Cu addition on the electrical and.....
More
Cited By 1
Ion Exchange for the Purification of Co(II) or Ni(II) from Acidic and Ammonia Solutions in the Recycling of Spent Lithium-Ion Batteries
Thanh Tuan Tran, Man Seung Lee
Korean J. Met. Mater.
2022;60(12):902-911. Published online 2022 Nov 25
DOI:
https://doi.org/10.3365/KJMM.2022.60.12.902
Abstract
The recycling of critical metals like cobalt and nickel from spent lithium-ion batteries (LIBs) is of immense importance in sustainable manufacturing. This work aims to purify Co(II) and Ni(II) present in acidic and ammonia solutions using ion exchange. AG-1-X8 resin modified with thiocyanate anions (R
4
N
+
SCN
−
resin) was used to separate.....
More
Cited By 1
Effects of V Alloying on Thermoelectric Properties of NbFeSb Half-Heusler Materials Codoped with Ti, Zr, and Sn
Sung-Jae Joo, JeongIn Jang, Ji-Hee Son, Bong-Seo Kim, Bok-Ki Min
Korean J. Met. Mater.
2022;60(11):858-864. Published online 2022 Oct 31
DOI:
https://doi.org/10.3365/KJMM.2022.60.11.858
Abstract
NbFeSb-based alloys are promising
p
-type half-Heusler materials with excellent thermoelectric performance, thermal stability, and naturally abundant constituent elements. Alloying and doping are powerful techniques for enhancing the thermoelectric properties of half-Heusler materials. This study experimentally investigated the effects of V alloying in NbFeSb codoped with Ti, Zr, and Sn. As.....
More
Electrospun Nanofiber-Based Electrodes Composed of Core-Shell (PVDF)-(Al) Structures for Application to Flexible Electronics
Heesung Park, Kwanlae Kim
Korean J. Met. Mater.
2022;60(10):760-768. Published online 2022 Sep 29
DOI:
https://doi.org/10.3365/KJMM.2022.60.10.760
Abstract
Nanostructured transparent conductors have been studied intensively for application to flexible and transparent electronic devices. Among diverse nanomaterials, electrospun nanofibers provide several advantages over other nanomaterials, including a high aspect ratio, uniform distribution, and a facile fabrication process. In the present study, an electrode composed of a core-shell (PVDF)-(Al) structured.....
More
Selective Extraction of Cu(II) from the Hydrochloric Acid Leaching Solution of Spent Lithium-Ion Batteries by a Mixture of Aliquat 336 and LIX 63
Jiangxian Wen, Man Seung Lee
Korean J. Met. Mater.
2022;60(10):751-759. Published online 2022 Sep 29
DOI:
https://doi.org/10.3365/KJMM.2022.60.10.751
Abstract
The smelting reduction of spent LIBs produces metallic alloys containing Co, Cu, Fe, Mn, and Ni. These metallic alloys can be completely dissolved by 2 M HCl solution containing H
2
O
2
as an oxidizing agent. Extraction of the leaching solution with D2EHPA results in a Fe(III) free raffinate. In this work,.....
More
Cited By 1
Fabrication and Surface Modification of Macroporous Silica Fibers by Electrospinning for Super Adsorbent of Oil
Hoai Han Nguyen, Thi Thu Hien Nguyen, Young-Sang Cho
Korean J. Met. Mater.
2022;60(10):732-743. Published online 2022 Sep 29
DOI:
https://doi.org/10.3365/KJMM.2022.60.10.732
Abstract
Silica fibers were fabricated by sol-gel reaction and an electrospinning process. A high voltage source of electricity was applied to the prepared spinning solution to form the fibers. Macroporous silica fibers were prepared using polystyrene (PS) nanospheres as templates after calcination. The pore size could be controlled by adjusting the.....
More
Cited By 2
Enhancing mechanical properties of Mg-Gd-Y-Zn alloys via microalloying with Ce and La
Zhaobin Zhang, Jonghyun Kim, Hongxin Liao, Ki Buem Kim, Taekjib Choi, Taekyung Lee, Fusheng Pan김기범, 최택집, 이태경,
Korean J. Met. Mater.
2022;60(9):654-667. Published online 2022 Aug 30
DOI:
https://doi.org/10.3365/KJMM.2022.60.9.654
Abstract
This study investigated the microstructure and mechanical properties of Mg-1Gd-1Y-1Zn (at.%) alloys containing designed amounts of Ce or La. The Mg
5
(Gd,Zn) phase formed in the as-cast Mg-Gd-Y-Zn-Ce/La alloys and disappeared after a homogenization treatment at 500°C for 24 h. The addition of Ce and La resulted in the formation of.....
More
Thermoelectric Performance of Sn and Bi Double-Doped Permingeatite
Hee-Jae Ahn, Il-Ho Kim
Korean J. Met. Mater.
2022;60(8):593-600. Published online 2022 Jul 12
DOI:
https://doi.org/10.3365/KJMM.2022.60.8.593
Abstract
In this study, mechanical alloying was performed to synthesize permingeatite Cu
3
Sb
1-x-y
Sn
x
Bi
y
Se
4
(0.02 ≤ x ≤ 0.06 and 0.02 ≤ y ≤ 0.04) doped with Sn and Bi. Hot pressing was subsequently conducted to achieve dense sintered bodies. When the Bi content was constant, the carrier concentration increased with the Sn.....
More
Physical Vapor Transport Process for Highly Purified Hg
2
Br
2
Crystal: from Powder Purification to Crystal Growth
Ojun Kwon, Yonghui Song, Shi-Gwan Woo, Woojin Park, Byungjin Cho
Korean J. Met. Mater.
2022;60(7):551-556. Published online 2022 Jun 3
DOI:
https://doi.org/10.3365/KJMM.2022.60.7.551
Abstract
High quality Hg
2
Br
2
crystal grown
via
the physical vapor transport (PVT) process is essential for the fabrication of the acousto-optic tunable filters (AOTFs) module. The full process flow, including powder purification and crystal growth, should be systematically established, but there have been few reports about the fully established process flow.....
More
Cited By 3
Enhanced Photoelectrochemical Water-Splitting through Application of Layer by Layer (LBL) and Hydrothermal (HT) Methods in TiO
2
and α-Fe
2
O
3
Hierarchical Structures
Aryan Azad, Sun Jae Kim
Korean J. Met. Mater.
2022;60(7):517-522. Published online 2022 Jun 3
DOI:
https://doi.org/10.3365/KJMM.2022.60.7.517
Abstract
Improving solar energy conversion efficiency and reducing energy loss have become critical issues in recent decades. Photoelectrochemical (PEC) water splitting provides an ideal method for solar energy harvesting and is a key factor in decreasing the use of fossil fuels. Thus, it is extremely important to identify cost-effective, highly active,.....
More
Cited By 2
Effect of Ethylene Glycol on the Dissolution of Palladium with HCl Solution Containing Oxidizing Agents and Selective Precipitation of Pd(IV) Compound
Viet Nhan Hoa Nguyen, Si Jeong Song, Man Seung Lee
Korean J. Met. Mater.
2022;60(7):502-510. Published online 2022 Jun 3
DOI:
https://doi.org/10.3365/KJMM.2022.60.7.502
Abstract
There is growing interest in the recovery of pure palladium (Pd) compound from cemented Pd from spent electroplating solutions due to increasing demand for Pd, and there is considerable motivation to develop an efficient recovery process. In conventional methods of leaching Pd metal, HCl solutions containing oxidizing agents are employed......
More
Cited By 2
Effect of Sn addition on the Microstructure and Friction–wear Properties of a Nodular Graphite Cast Iron
Won-Sang Shin, Seungwoo Baek, Yoon-Jun Kim
Korean J. Met. Mater.
2022;60(6):471-477. Published online 2022 May 24
DOI:
https://doi.org/10.3365/KJMM.2022.60.6.471
Abstract
Nodular graphite cast iron is used in the railway and automobile industries because of its excellent workability, abrasion resistance, mechanical strength, and hardenability. To use nodular graphite cast iron in harsh environments, it is essential to examine their friction–wear properties in conjunction with the surface hardness of the materials. Therefore,.....
More
Cited By 4
Skinnerite Cu
3
SbS
3
: Solid-State Synthesis and Thermoelectric Properties
Go-Eun Lee, Il-Ho Kim
Korean J. Met. Mater.
2022;60(6):455-462. Published online 2022 May 24
DOI:
https://doi.org/10.3365/KJMM.2022.60.6.455
Abstract
Skinnerite Cu
3
SbS
3
, which consists of non-toxic and low-cost elements, is a potential thermoelectric material, however, studies on its thermoelectric properties are limited. In this study, the optimal conditions of mechanical alloying (MA) and hot pressing (HP) for the synthesis of the Cu
3
SbS
3
phase were investigated, and its thermoelectric properties were.....
More
Cited By 3
Preparation and Thermoelectric Properties of Si-Doped Tetrahedrites Cu
12
Sb
4-y
Si
y
S
13
Min-Cheol Kwon, Il-Ho Kim
Korean J. Met. Mater.
2022;60(6):440-447. Published online 2022 May 24
DOI:
https://doi.org/10.3365/KJMM.2022.60.6.440
Abstract
Si-doped Cu
12
Sb
4-y
Si
y
S
13
(y = 0.1-0.4) compounds were prepared using solid-state synthesis. Each specimen consisted of a single tetrahedrite phase with a densely sintered body whose relative density exceeded 98.9%. The lattice constant decreased from 1.0357 nm to 1.0336 nm as the Si content increased. When the Si doping content (y).....
More
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