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Investigation of the Calciothermic Reduction of TiO<sub>2</sub> for the Green Production of Ti and TiH<sub>2</sub> Powders
친환경 Ti 및 TiH2 분말 제조를 위한 TiO2의 칼슘열환원에 대한 기초연구
Sung-Hun Park, Jungshin Kang, Ho-Sang Sohn
박성훈, 강정신, 손호상
Korean J. Met. Mater. 2024;62(3):190-203.   Published online 2024 Feb 28
DOI: https://doi.org/10.3365/KJMM.2024.62.3.190

Abstract
To develop an eco-friendly titanium (Ti) production process, the calciothermic reduction of titanium dioxide (TiO2) was investigated. The mechanism involved in the reduction of TiO2 using calcium (Ca) was examined. The influence of a molten salt, calcium chloride (CaCl2), on the calciothermic reduction was investigated by conducting experiments at 1123..... More

                
Simultaneous Removal of Gas-Phase Pollutants CO and NO Using Ni-Fe Bimetallic Oxides Catalyst
Ni-Fe bimetallic oxides 촉매의 CO, NO 가스상 오염물질 동시저감 특성
Woon-Gi Kim, Jae-Il Jung, Myeung-Jin Lee, Bora Jeong, Bora Ye, Heesoo Lee, Hong-Dae Kim
김운기, 정재일, 이명진, 정보라, 예보라, 이희수, 김홍대
Korean J. Met. Mater. 2024;62(2):115-124.   Published online 2024 Jan 30
DOI: https://doi.org/10.3365/KJMM.2024.62.2.115

Abstract
Many studies have been conducted on methods to remove air pollutants. Among them, a representative commercial technology for reducing nitrogen oxides (NOX) is selective catalytic reduction (SCR) using NH3 as a reductant. However, the NH3-SCR technology has problems, such as the need for additional NH3 gas (Active-SCR), the fact that..... More

                
Review of Electro-catalysts Supported by Metal Oxides for Electrochemical Oxygen Reduction Reaction
금속 산화물 지지체를 이용한 산소환원반응에 대한 전기화학 촉매 연구 동향
Yoo-Jin Jo, Won Suk Jung, Boyoung Lim
조유진, 정원석, 임보영
Korean J. Met. Mater. 2023;61(4):231-241.   Published online 2023 Mar 22
DOI: https://doi.org/10.3365/KJMM.2023.61.4.231

Abstract
Global warming and air pollution have forced greater attention to new energy sources to replace fossil fuels. Among several eco-friendly energy sources, polymer electrolyte membrane fuel cells have been increasingly investigated since they have zero emissions, high energy density, and high energy efficiency. Carbon-supported Pt catalyst is generally used for..... More

                   Crossref 1
Bandgap Reduction and Enhanced Photoelectrochemical Water Electrolysis of Sulfur-doped CuBi<sub>2</sub>O<sub>4</sub> Photocathode
Eunhwa Kim, Sanghan Lee, Sangwoo Ryu
Korean J. Met. Mater. 2023;61(2):115-119.   Published online 2023 Jan 27
DOI: https://doi.org/10.3365/KJMM.2023.61.2.115

Abstract
As interest in hydrogen energy grows, eco-friendly methods of producing hydrogen are being explored. CuBi2O4 is one of the p-type semiconductor cathode materials that can be used for photoelectrochemical hydrogen production via environment-friendly water electrolysis. CuBi2O4 has a bandgap of 1.5 – 1.8 eV which allows it to photogenerate electrons..... More

                
Recovery of Palladium Metal with High Purity by Selective Reduction from Inorganic Acid Leaching Solutions of Cemented Zinc
아연치환체의 무기산 침출액에서 선택적 환원에 의한 고순도 팔라듐금속의 회수
Si Jeong Song, Viet Nhan Hoa Nguyen, Man Seung Lee
송시정, Viet Nhan Hoa Nguyen, 이만승
Korean J. Met. Mater. 2022;60(11):837-844.   Published online 2022 Oct 31
DOI: https://doi.org/10.3365/KJMM.2022.60.11.837

Abstract
A small amount of Pd(II) present in spent electroplating solutions is concentrated by cementation. In this work, a process was developed to recover pure palladium metal by selective reduction from the hydrochloric and the sulfuric acid leaching solutions of cemented zinc. For this purpose, hydrazine and ascorbic acid were employed..... More

                   Web of Science 1  Crossref 1
Synthesis of N-type Bi<sub>2</sub>Te<sub>2.7</sub>Se<sub>0.3</sub> Compounds through Oxide-Reduction Process and Related Thermoelectric Transport Properties
산화물 환원공정에 의한 n형 Bi2Te2.7Se0.3 화합물의 합성과 열전특성
Young Soo Lim, Bae Gun Park, Gil-Geun Lee
임영수, 박배건, 이길근
Korean J. Met. Mater. 2022;60(6):463-470.   Published online 2022 May 24
DOI: https://doi.org/10.3365/KJMM.2022.60.6.463

Abstract
We present a study on the synthesis of Bi2Te2.7Se0.3 powders through an oxide reduction process and also on the effect of the oxide reduction process on the thermoelectric transport properties of the resulting Bi2Te2.7Se0.3 compounds. Starting materials of Bi2O3, TeO2 and SeO2 were mechanical milled for homogeneous mixing, and then..... More

                   Web of Science 5  Crossref 6
Recent Studies on Bimetallic PtM Catalyst for the Oxygen Reduction Reaction in Polymer Electrolyte Membrane Fuel Cells
고분자 전해질 연료전지의 산소환원반응에 대한 Pt-M 합금 촉매의 최근 연구 동향
Yu-Jin Shim, Won Suk Jung
심유진, 정원석
Korean J. Met. Mater. 2021;59(10):741-752.   Published online 2021 Sep 6
DOI: https://doi.org/10.3365/KJMM.2021.59.10.741

Abstract
Due to environmental pollution and global warming, research on new energy sources that can replace fossil fuels is important. A fuel cell is an eco-friendly energy conversion system that discharges water, and uses hydrogen as fuel. Although platinum is a widely used catalyst in PEMFCs, it has commercial limitations because..... More

                   Crossref 2
Microstructure and Sintering Behavior of Fine Tungsten Powders Synthesized by Ultrasonic Spray Pyrolysis
초음파 분무 열분해법으로 제조한 텅스텐 미세분말의 미세조직과 소결 거동
Hyeonhui Jo, Jeong Hyun Kim, Young-In Lee, Young-Keun Jeong, Sung-Tag Oh
조현희, 김정현, 이영인, 정영근, 오승탁
Korean J. Met. Mater. 2021;59(5):289-294.   Published online 2021 Apr 6
DOI: https://doi.org/10.3365/KJMM.2021.59.5.289

Abstract
The powder microstructure and sintering behavior of W prepared by ultrasonic spray pyrolysis and spark plasma sintering were investigated. Fine-grained W powders were synthesized by ultrasonic spray pyrolysis using an ammonium metatungstate hydrate solution and hydrogen reduction. The XRD analysis of the powder, pyrolyzed below 600 oC, showed tungsten oxide..... More

                   Web of Science 2  Crossref 2
Hydrogen-Based Reduction Ironmaking Process and Conversion Technology
수소 기반 환원 제철 공정과 전환 기술
Sang-Ho Yi, Woon-Jae Lee, Young-Seok Lee, Wan-Ho Kim
이상호, 이운재, 이영석, 김완호
Korean J. Met. Mater. 2021;59(1):41-53.   Published online 2021 Jan 5
DOI: https://doi.org/10.3365/KJMM.2021.59.1.41

Abstract
This study analyzed the current state of technical development of the BF-based process, to determine ways to reduce carbon consumption. The technical features of the hydrogen reduction ironmaking process were also examined as a decarbonized ironmaking method, and related issues that should be considered when converting to hydrogen reduction are..... More

                   Web of Science 15  Crossref 14
Facile Synthesis of Single-Phase Alpha-Tungsten Nanopowders from Ammonium Paratungstate by RF Induction Thermal Plasma and Thermochemical Reduction
Dongyoon Shin, Hyun-Woo Shim, Basudev Swain, Kyung-Soo Park, Chan-Gi Lee
Korean J. Met. Mater. 2020;58(11):798-807.   Published online 2020 Oct 15
DOI: https://doi.org/10.3365/KJMM.2020.58.11.798

Abstract
Facile, economic methods of preparing tungsten (W) nanopowder are critically needed to meet industrial demand. Herein, we report a method of preparing single-phase alpha-W (α-W) nanopowders using ammonium paratungstate (APT) as a starting material and the optimum synthesis conditions. The process involves two stages: i) the radio-frequency (RF) induction thermal..... More

                   Web of Science 4  Crossref 4
The Study on the Manufacturing Cold Cured Briquette Using Curing Reaction of Sodium Silicate
규산 소다의 경화 반응을 이용한 상온 경화 괴성광 제조에 대한 연구
Kang-Min Kim, Jeong-Whan Han
김강민, 한정환
Korean J. Met. Mater. 2020;58(6):369-374.   Published online 2020 May 20
DOI: https://doi.org/10.3365/KJMM.2020.58.6.369

Abstract
New technologies need to be developed in the ironmaking process to reduce carbon dioxide emissions. To achieve this, in recent years steelmakers have been working to reduce coke usage by increasing thermal energy efficiency. However, it is very difficult to reduce coke consumption while maintaining production, because the level of..... More

                
Thermoelectric Transport Properties of N-type Bi<sub>2</sub>Te<sub>2.7</sub>Se<sub>0.3</sub> Compound Prepared by Oxide-Reduction Process
산화물 환원공정에 의해 제작된 n-형 Bi2Te2.7Se0.3 화합물의 열전특성연구
Young Soo Lim, Bae Gun Park, Gil-Geun Lee
임영수, 박배건, 이길근
Korean J. Met. Mater. 2020;58(5):334-339.   Published online 2020 Apr 20
DOI: https://doi.org/10.3365/KJMM.2020.58.5.334

Abstract
We report the thermoelectric transport properties of n-type Bi2Te2.7Se0.3 compounds prepared by oxide-reduction process. The oxide-reduction process is a recently developed method that can synthesize Bi2Te3-based compounds using only oxide starting materials, which is advantageous in terms of the diversity of the starting materials and cost efficiency. In this study,..... More

                   Web of Science 3  Crossref 4
Photocatalytic Characterization of TiO<sub>2</sub> Nanotubes with Pd Particles Synthesized by Photoreduction Process
광환원반응을 통한 TiO2/Pd 복합광촉매 제조와 광촉매 특성
Jong-Ho Lee, Hong-Joo Ahn, Jeong-Il Youn, Young-Jig Kim, Su-Jeong Suh, Han-Jun Oh
이종호, 안홍주, 윤정일, 김영직, 서수정, 오한준
Korean J. Met. Mater. 2019;57(8):510-520.   Published online 2019 Jul 8
DOI: https://doi.org/10.3365/KJMM.2019.57.8.510

Abstract
To decompose dye in aqueous solution, Pd nanoparticle-decorated TiO2 nanotube photocatalysts were fabricated through electrochemical anodization and photoreduction processes. Morphological and surface characterization of the TiO2/Pd heterojunction photocatalyst, as well as photoelectrochemical behaviors, were investigated by X-ray diffraction, UV/Vis diffuse reflectance and photocurrent response. It was found that the precipitated..... More

                   Web of Science 5  Crossref 3
Tin Microcrystals Synthesized by Thermal Chemical Vapor Deposition in a Hydrogen-Reducing Atmosphere
Daseul Ham, Won Jeong, Hyon Chol Kang
Korean J. Met. Mater. 2019;57(6):390-395.   Published online 2019 May 16
DOI: https://doi.org/10.3365/KJMM.2019.57.6.390

Abstract
We demonstrate a synthetic route to high-quality Sn microcrystals using thermal chemical vapor deposition (CVD) in a hydrogen-reducing atmosphere. During thermal CVD with SnO2 powder, a mixture of Ar and H2 (4%) gases was used as a carrier gas to maintain a hydrogen reduction environment. Hydrogen maintained a reduction environment..... More

                   Web of Science 2  Crossref 2
Adsorption / Desorption Performance and NOx Removal Efficiency of BaO Loaded V2O5-WO3/TiO2 Selective Catalytic Reduction Catalyst
BaO가 담지된 V2O5-WO3/TiO2 SCR 촉매의 질소산화물 흡, 탈착 특성 및 제거 효율
Jin Woo Kim, Bora Ye, Minwoo Lee, Bora Jung, Duck Hyun Lee, Heesoo Lee, Hong-Dae Kim
김진우, 예보라, 이민우, 정보라, 이덕현, 이희수, 김홍대
Korean J. Met. Mater. 2019;57(4):270-277.   Published online 2019 Apr 5
DOI: https://doi.org/10.3365/KJMM.2019.57.4.270

Abstract
Recently, directly emitted NOx upon start-up has been spotlighted as a significant emissions problem. BaO loaded V2O5-WO3/TiO2 Selective Catalytic Reduction (SCR) catalysts were synthesized with various contents of barium which was a representative NOx adsorbent and their NOx adsorption, desorption, and removal efficiency were shown. The phase of BaO was..... More

                   Web of Science 3  Crossref 4
Modification of the Amount of CH<sub>4</sub> Supplied for the Efficient CH<sub>4</sub> Reduction of SnO<sub>2</sub>
Taeyang Han, Youhan Sohn, Hyunwoo Ha, Mi Yoo, Sangyeol Kim, Sang-ro Lee, Hyun You Kim, Jun Hyun Han
Korean J. Met. Mater. 2018;56(5):384-391.   Published online 2018 May 8
DOI: https://doi.org/10.3365/KJMM.2018.56.5.384

Abstract
The methane reduction (MR) of SnO2 has been proposed as a highly efficient method for recovering Sn from SnO2 containing industrial wastes. The MR of SnO2 also produces a mixture of H2 and CO, which can be further utilized as a syngas for the production of various fuels through the..... More

       Crossref 2
Hydrogen Embrittlement of Three High-Manganese Steels Tested by Different Hydrogen Charging Methods
수소 주입 방식에 따른 세 고망간강의 수소 취화 거동 비교
Seung-Yong Lee, Byoungchul Hwang
이승용, 황병철
Korean J. Met. Mater. 2017;55(10):695-702.   Published online 2017 Sep 28
DOI: https://doi.org/10.3365/KJMM.2017.55.10.695

Abstract
In this study the hydrogen embrittlement characteristics of three high-manganese steels were tested using different hydrogen charging methods, and the results were compared with various Mn-containing steels. The results showed that the hydrogen embrittlement susceptibility of the high-manganese steels increased with increasing inherent strength because deformation mechanisms, such as deformation..... More

    
Properties of the Catalytic Nickel Silicides for a Dye-Sensitized Solar Cell
염료감응형 태양전지용 니켈실리사이드 촉매재료의 물성 연구
Taeyeul Park, Kwangbae Kim, Ohsung Song
박태열, 김광배, 송오성
Korean J. Met. Mater. 2017;55(6):440-445.   Published online 2017 Jun 1
DOI: https://doi.org/10.3365/KJMM.2017.55.6.440

Abstract
We have investigated the properties of nickel silicides as catalysts for dye-sensitized solar cells (DSSCs) by preparing several nickel silicide layers with a 100 nm-Ni/Si (100) structure using silicidation annealing for 30 minutes at 300 ℃ – 900 ℃. X-ray diffraction (XRD), four-point probe, field emission scanning electron microscope (FE-SEM),..... More

       Crossref 1
Reduction Behaviors of Carbon Composite Iron Oxide Briquette Under Oxidation Atmosphere
산화성분위기에서의 탄재 내장 산화철 브리켓의 환원특성
Ki-Woo Lee, Kang-Min Kim, Jae-Hong Kwon, Sang-Han Son, Jeong-Whan Han
이기우, 김강민, 권재홍, 손상한, 한정환
Korean J. Met. Mater. 2017;55(1):24-30.   Published online 2017 Jan 5
DOI: https://doi.org/10.3365/KJMM.2017.55.1.24

Abstract
The carbon composite iron oxide briquette (CCB) is considered a potential solution to the upcoming use of low grade iron resources in the ironmaking process. CCB is able to reduce raw material cost by enabling the use of low grade powdered iron ores and coal. Additionally, the fast reduction of..... More

    
Effect of Basicity on the Reduction Behavior of Carbon Composite Iron Oxide Briquette
탄재내장 산화철 브리켓의 환원거동에 미치는 염기도 영향
Jae-Hong Kwon, Eui-Hyuk Kwon, Ki-Woo Lee, Kang-Min Kim, Ji-A Lee, Jeong-Whan Han
권재홍, 권의혁, 이기우, 김강민, 이지아, 한정환
Korean J. Met. Mater. 2016;54(11):846-854.   Published online 2016 Nov 5
DOI: https://doi.org/10.3365/KJMM.2016.54.11.846

Abstract
The world is gradually running short of high quality iron resources. This forces ironmaking processes to focus on the use of low quality iron ores. Carbon composite iron oxide briquettes (CCB) are one of the alternative choices. CCB enables the utilization of low quality powdered iron ores and coal, and..... More

       Crossref 1
Carbothermal Reduction of Oxide of WC/Co Hardmetal Scrap
WC/Co 초경 스크랩 산화물의 환원/침탄 반응
CheolMin Kwon, Gil-Geun Lee, Gook-Hyun Ha
권철민, 이길근, 하국현
Korean J. Met. Mater. 2016;54(10):743-751.   Published online 2016 Oct 5
DOI: https://doi.org/10.3365/KJMM.2016.54.10.743

Abstract
This study conducted an analysis of the carbothermal reduction of oxidized WC/Co hardmetal scrap with solid carbon under an argon and hydrogen gas atmosphere. The WC/Co hardmetal scrap oxide consisted of WO3 and CoWO4. WO3 was reduced before CoWO4 by the solid carbon regardless of gas atmosphere. The simple oxide..... More

       Crossref 3
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